Legenda do estouro do subfig na coluna oposta (Overfull hbox)

Question

Ao usar o pacote subfig e \subfloata legenda vai para a coluna oposta. Anexei um exemplo prático.

\documentclass[10pt, twocolumn]{revtex4}    % Font size (10,11 or 12pt) and column number (one or two).

\usepackage[a4paper, left=1.85cm, right=1.85cm,
 top=1.85cm, bottom=1.85cm]{geometry}       % Defines paper size and margin length

\usepackage[font=small,
labelfont=bf]{caption}                      % Defines caption font size as 9pt and caption title bolded
\usepackage[font=small]{subfig}
\usepackage{pgfplots}
\usepackage{tikz}
\usepackage[font=small]{subfig}
\usepgfplotslibrary{external} 
\tikzexternalize


\begin{document}

\begin{figure}
    \centering
    \subfloat[Long caption long caption long caption long caption long caption long caption long caption long caption long caption long caption long caption long caption long caption long caption long caption long caption long caption.]{
    \label{fig:sub:derivs}
    \input{derivsboth.pgf}
}

    \centering
    \subfloat[Caption caption caption caption caption caption caption caption caption caption caption caption caption caption caption caption caption caption caption caption caption caption caption  ]{       
    \label{fig:sub:initialderiv}
    \input{initialderiv.pgf}
}
    \caption{Main caption main caption main caption main caption main caption main caption main caption main caption main caption main caption main caption main caption main caption main caption }
    \label{fig:full:derivs}
\end{figure}

Meu entendimento é que os colchetes subfloatpodem ser usados ​​como legendas. Isso é intencional/devo fazer algo diferente? Desde já, obrigado!